BCECE Medical BCECE Medical Solved Papers-2002

  • question_answer
    The boiling point of phenols are higher than the hydrocarbons of comparable masses due to:

    A)  more polarising power

    B)  presence of hydrogen bonding

    C)  resonance stabilisation

    D)  acidic character

    Correct Answer: B

    Solution :

    Key Idea: Hydrogen bonds are strong forces of attraction existing among molecules having 0 or N or F with H. They are as stronger as compared to van der Waals forces of attraction Phenols have hydrogen bonding between molecules which is stronger than van der Waals forces of attraction exisiting between molecules of hydrocarbons. So the phenols have higher boiling points than hydrocarbons.


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