BCECE Medical BCECE Medical Solved Papers-2004

  • question_answer
    \[C{{H}_{3}}C{{H}_{2}}OH\] convert into \[C{{H}_{3}}CHO\] in the presence of:

    A)  \[N{{a}_{2}}C{{r}_{2}}{{O}_{7}}\] and \[NaOH\]

    B)  \[N{{a}_{2}}C{{r}_{2}}{{O}_{7}}\] and dil. \[{{H}_{2}}S{{O}_{4}}\]

    C)  \[NaOH\]

    D)  Fe in presence of \[NaOH\]

    Correct Answer: B

    Solution :

    Key Idea: \[{{1}^{o}}\] alcohol are converted into aldehyde by reaction with \[N{{a}_{2}}C{{r}_{2}}{{O}_{7}}\] and \[{{H}_{2}}S{{O}_{4}}\] \[\underset{ethyl\text{ }alcohol}{\mathop{C{{H}_{3}}C{{H}_{2}}OH}}\,+[O]\xrightarrow{N{{a}_{2}}C{{r}_{2}}{{O}_{7}}+{{H}_{2}}S{{O}_{4}}}\] \[\underset{ethanal}{\mathop{C{{H}_{3}}CHO}}\,+{{H}_{2}}O\]


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