BCECE Medical BCECE Medical Solved Papers-2005

  • question_answer
    pH of \[{{10}^{-8}}M\,HCl\] solution is:

    A)  8

    B)  between 7 and 8

    C)  between 6 and 7

    D)  between 8 and 9

    Correct Answer: C

    Solution :

    Key Idea: In a dilute solution, the \[{{H}^{+}}\] furnished by water cannot be neglected Given    \[HCl={{10}^{-8}}M\]                 \[\underset{{{10}^{-8}}}{\mathop{HCl}}\,\xrightarrow{{}}\underset{{{10}^{-8}}}{\mathop{{{H}^{+}}}}\,+\underset{{{10}^{-8}}}{\mathop{C{{l}^{-}}}}\,\]                 \[{{H}_{2}}O\underset{{{10}^{-7}}}{\mathop{{{H}^{+}}}}\,\,\,+\underset{{{10}^{-7}}}{\mathop{O{{H}^{-}}}}\,\] \[\therefore \] Total \[[{{H}^{+}}]={{10}^{-7}}+{{10}^{-8}}\]                 \[={{10}^{-7}}(1+{{10}^{-1}})\]                 \[pH=-\log \,\,[{{H}^{+}}]\]                 \[=-\log \,\,{{10}^{-7}}\,(1+{{10}^{-1}})\]                 = 6.98 \[\therefore \] The pH is between 6 and 7.


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