BCECE Medical BCECE Medical Solved Papers-2013

  • question_answer
    Identify [A] and [B] in the following sequence of reactions. \[SnC{{l}_{2}}+2NaOH\xrightarrow{{}}(A)\,\] (white ppt) \[\xrightarrow[(excess)]{NaOH}(B)\]

    A)  \[Sn{{(OH)}_{2}},\,N{{a}_{2}}Sn{{O}_{3}}\]

    B)  \[Sn{{(OH)}_{2}},\,N{{a}_{2}}Sn{{O}_{2}}\]

    C)  \[Sn{{(OH)}_{2}},\,N{{a}_{2}}[Sn{{[OH)}_{2}}]\]

    D)  \[Sn{{(OH)}_{2}}\], no effect

    Correct Answer: B

    Solution :

    \[SnC{{l}_{2}}+2NaOH\xrightarrow{{}}\underset{white\text{ }ppt}{\mathop{Sn{{(OH)}_{2}}\downarrow }}\,+2NaCl\] \[Sn{{(OH)}_{2}}+2NaOH\xrightarrow{{}}\underset{sodium\text{ }stannite}{\mathop{N{{a}_{2}}Sn{{O}_{2}}}}\,\]


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