BCECE Medical BCECE Medical Solved Papers-2015

  • question_answer
    Compound A undergoes following reactions to form B and C Black coloured solid [A] \[\xrightarrow{KN{{O}_{3}}+KOH}\] Green coloured solution [B] Green coloured \[\xrightarrow{C{{O}_{2}}}\] Pink solution[C] + [A] Solution [B] [C] decolourised by \[F{{e}^{3+}}\] Identify A, B and C respectively

    A)  \[Mn{{O}_{2}},\,KMn{{O}_{4}}\] and \[{{K}_{2}}Mn{{O}_{4}}\]

    B)  \[Mn{{O}_{2}},\,{{K}_{2}}Mn{{O}_{4}}\] and \[KMn{{O}_{4}}\]

    C)  \[KMn{{O}_{4}},\,Mn{{O}_{2}}\] and \[{{K}_{2}}Mn{{O}_{4}}\]

    D)  \[KMn{{O}_{4}},\,{{K}_{2}}Mn{{O}_{4}}\] and \[Mn{{O}_{2}}\]

    Correct Answer: B

    Solution :

    \[\underset{\text{(}Black)\text{ }A}{\mathop{Mn{{O}_{2}}}}\,+KOH+KN{{O}_{3}}\xrightarrow{\Delta }\underset{Green}{\mathop{{{K}_{2}}Mn{{O}_{4}}(B)}}\,\] \[C{{O}_{2}}+{{H}_{2}}O{{H}_{2}}C{{O}_{3}}{{H}^{+}}+HCO_{3}^{-}\] \[\times {{p}^{o}}=\frac{5.278}{5.361}\times 23.5\]


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