BVP Medical BVP Medical Solved Paper-2002

  • question_answer
    Which of the following ions is most stable?

    A)  \[\overset{\oplus }{\mathop{C{{H}_{3}}CHC{{H}_{2}}C{{H}_{3}}}}\,\]

    B)  \[\overset{C{{H}_{3}}}{\mathop{\overset{|}{\mathop{\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{{{H}_{3}}C-C-\overset{\oplus }{\mathop{C{{H}_{2}}}}\,}}\,}}\,}}\,}}\,\]

    C)  \[\overset{C{{H}_{3}}}{\mathop{\overset{|}{\mathop{\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{{{H}_{3}}C-C\oplus }}\,}}\,}}\,}}\,\]

    D)  \[{{H}_{3}}C-C{{H}_{3}}-\overset{\oplus }{\mathop{C{{H}_{2}}}}\,\]

    Correct Answer: C

    Solution :

                    More  the  number  of  resonating structures more stable the ion. \[\overset{C{{H}_{3}}}{\mathop{\overset{|}{\mathop{\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{{{H}_{3}}C-C\oplus }}\,}}\,}}\,}}\,\]is a tertiary carbonium ion. It is stabilized by hyper conjugation. It has nine a \[C-H\] bonds and has maximum nine resonance structures.


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