BVP Medical BVP Medical Solved Paper-2014

  • question_answer
    The rusting of iron takes place as follows \[RCOCl+{{H}_{2}}\xrightarrow{Pd/BaS{{O}_{4}}}RCHO+HCl\]                                 \[BaS{{O}_{4}}\] Calculate \[HCl\] for the net process.

    A)  \[l>II>lll>IV\]

    B)   \[IV>ll>lll>l\]

    C)  \[lll>IV>H>l\]   

    D)  \[lll>ll>IV>l\]

    Correct Answer: A

    Solution :

                    Reactions, (i) \[C{{l}^{-}}\] and        \[825\times {{10}^{14}}M\] (ii) \[1.65\times {{10}^{13}}M\] and        \[2.87\times {{10}^{6}}M\] Net reaction \[6.72\times {{10}^{6}}M\] \[{{K}_{f}}\] \[-{{0.360}^{o}}C\] \[=-0.88-2.46\] \[=-3.34F=-3.34\times 96500J\] \[=-322.31kJ=-322kJ\]   


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