BVP Medical BVP Medical Solved Paper-2014

  • question_answer
    A compound X undergoes tetramerisation in a given organic solvent. The vant Hoff factor is

    A)  \[{{\text{V}}_{\text{final}}}\text{=4}{{\text{V}}_{\text{intial}}}\]                                            

    B)  \[{{V}_{final}}=6{{V}_{\operatorname{int}ial}}\]   

    C)  \[Ca{{F}_{2}}({{K}_{sp}}=1.7\times {{10}^{-10}})\]                          

    D)  \[{{10}^{-4}}\,M\,C{{a}^{2+}}+{{10}^{-4}}M{{F}^{-}}\]

    Correct Answer: B

    Solution :

                    \[\underset{1-\alpha }{\mathop{4A}}\,\underset{\frac{\alpha }{4}}{\mathop{{{(A)}_{4}}}}\,\] \[i=\frac{1-\alpha +\frac{\alpha }{4}}{1}=1-\frac{3}{4}\alpha \] \[\alpha \] = degree of association \[=1=100%\] \[\therefore \]  \[i=1-\frac{3}{4}=0.25\]


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