BVP Medical BVP Medical Solved Paper-2015

  • question_answer
    Which of the following buffer solution turns invalid on addition of 10 mL of \[{{25}^{o}}C\]?

    A)   \[C{{H}_{3}}COOH\] having \[N{{H}_{4}}OH\] \[({{10}^{-5}})\] and \[({{10}^{-5}})\] each

    B)  \[N{{H}_{4}}OH\] having \[4.0\] and \[3.0\] \[11.0\]each

    C)  \[10.0\] having \[\overset{O}{\mathop{\overset{||}{\mathop{C{{H}_{3}}-C-C{{H}_{2}}-C{{H}_{2}}-COOH}}\,}}\,\]\[\xrightarrow[(ii)\,\,{{H}_{2}}O+{{H}^{+}}]{(i)\,\,NaB{{H}_{4}}}\]  and \[\beta \] each

    D)  \[\alpha \] having\[\alpha \]  \[\beta \]and \[\beta \]each

    Correct Answer: A

    Solution :

                    Mill moles of \[C{{H}_{3}}Mgl+C{{H}_{3}}COC{{H}_{3}}\]millimol Added \[C{{H}_{3}}C{{H}_{2}}MgBr+C{{H}_{3}}CHO\] millimol \[C{{H}_{3}}C{{H}_{2}}MgBr+C{{H}_{3}}COC{{H}_{3}}\]gets completely neutralised that means solution turns acidic, so thats not the buffer solution.


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