| I. \[p{{H}_{1}}>p{{H}_{2}}>>p{{H}_{3}}>p{{H}_{4}}\] |
| II. \[p{{H}_{1}}>p{{H}_{2}}>p{{H}_{3}}>p{{H}_{4}}\] |
| III. \[p{{H}_{1}}<p{{H}_{2}}<p{{H}_{3}}>>p{{H}_{4}}\] |
A) \[p{{H}_{1}}<p{{H}_{2}}<p{{H}_{3}}<p{{H}_{4}}\]
B) \[{{P}_{T}}={{x}_{1}}p_{1}^{0}+{{x}_{2}}p_{2}^{0}\]
C) \[{{P}_{T}}=(1-{{x}_{2}})p_{1}^{0}+{{x}_{2}}p_{2}^{0}\]
D) \[{{P}_{T}}=p_{1}^{0}+(p_{2}^{0}-p_{1}^{0}){{x}_{2}}\]
Correct Answer: D
Solution :
The value of \[{{\Delta }_{O}}\] for mixed ligands depends on the additive contributions of the ligand strength. Hence, \[C{{N}^{-}}\] has greater ligand strength than \[{{H}_{2}}O\], the strength increases as the number of \[C{{N}^{-}}\] ions increases
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