CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2000

  • question_answer
    The beta and alpha glucose have different specific rotations. When either is dissolved in water, their rotation changes until the same fixed value results. This is called:

    A)  epimerization  

    B)         racemization

    C)  anomerization 

    D)         mutarotation

    E)  inversion

    Correct Answer: D

    Solution :

    The\[\beta \]and\[\alpha -\]glucose have different specific rotations. When either is dissolved in water, their rotation changes until the same fixed value results. This is called mutarotation. \[\underset{Specific\text{ }rotation=+111{}^\circ }{\mathop{\alpha -D-glucose}}\,\underset{\begin{smallmatrix}  specific=+52.5{}^\circ  \\  of\text{ }equilibrium\text{ }mixture \end{smallmatrix}}{\mathop{open\,chain\,form}}\,\] \[\underset{specific\text{ }rotation=+19.2{}^\circ }{\mathop{\beta -D-glucose}}\,\]


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