CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2001

  • question_answer
    The metal that dissolves in liquid ammonia, giving a dark blue coloured solution is:

    A) tin                          

    B)        lead

    C) sodium                

    D)        silver

    E) zinc

    Correct Answer: C

    Solution :

    Alkali metals dissolve in liquid\[N{{H}_{3}}\]giving deep blue solution. The colour deepens with increase in concentration of the solution. When the alkali metals are dissolved in liquid. \[N{{H}_{3}},\]the ammonia molecule solvate the cation as well as the electron as: \[M+\underset{(excess)}{\mathop{N{{H}_{3}}}}\,\xrightarrow[{}]{{}}{{M}^{+}}{{(N{{H}_{3}})}_{x}}+\underset{\begin{smallmatrix}  ammoniated \\  \,\,\,\,electron \end{smallmatrix}}{\mathop{{{e}^{-}}{{(N{{H}_{3}})}_{x}}}}\,\] The blue colour of the solution is due to the ammoniated   electrons.   Due   to   these ammoniated electrons these solution also behaves as strong reducing agents.


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