CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2003

  • question_answer
    A saturated solution of\[Ca{{F}_{2}}\]is\[2\times {{10}^{-4}}mol/L\] Its solubility product constant is:

    A)  \[2.6\times {{10}^{-9}}\]     

    B)         \[4\times {{10}^{-8}}\]

    C)  \[8\times {{10}^{-12}}\]              

    D)         \[3.2\times {{10}^{-11}}\]

    E)  \[8\times {{10}^{-10}}\]

    Correct Answer: D

    Solution :

    Solubility of \[Ca{{F}_{2}}=2\times {{10}^{-4}}mol\,{{L}^{-1}}\] Each mole of\[Ca{{F}_{2}}\]dissolving in\[{{H}_{2}}O\]gives one mole of\[C{{a}^{2+}}\]and two moles of\[{{F}^{-}}\]ions. \[Ca{{F}_{2}}C{{a}^{2+}}+2{{F}^{-}}\]                 \[2\times {{10}^{-4}}M.2\times 2\times {{10}^{-4}}M\]                 \[{{K}_{sp}}=[C{{a}^{2+}}]{{[{{F}^{-}}]}^{2}}\]                 \[=[2\times {{10}^{-4}}]{{[2\times 2\times {{10}^{-4}}]}^{2}}\]                 \[{{K}_{sp}}=3.2\times {{10}^{-11}}\]


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