CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2004

  • question_answer
    The dissociation constant of acetic acid\[{{K}_{a}}\]is \[1.74\times {{10}^{-5}}\]at 298 K. The pH of a solution of 0.1 M acetic acid is:

    A)  2.88                                      

    B)  3.6

    C)  4.0                        

    D)         1.0

    E)  2.0

    Correct Answer: A

    Solution :

    For\[0.1M\]acetic acid, or \[C=0.1\,J{{K}^{-1}}mo{{l}^{-1}}\] \[{{K}_{a}}=1.74\times {{10}^{-5}}\] \[pH=?\] According to Ostwald dilution formula, \[[{{H}^{+}}]=\sqrt{{{K}_{a}}\times C}\]                 \[=\sqrt{1.7\times {{10}^{-5}}\times 0.1}\]                 \[=\sqrt{0.017\times {{10}^{-4}}}\]                 \[pH=-{{\log }_{10}}[{{H}^{+}}]\]                 \[=-{{\log }_{10}}[\sqrt{0.017\times {{10}^{-4}}}]\]                 \[pH=2.88\]


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