CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2006

  • question_answer
    Calculate the equilibrium constant for the reaction, at\[25{}^\circ C\] \[Cu(s)+2A{{g}^{+}}(aq)\xrightarrow[{}]{{}}C{{u}^{2+}}(aq)+2Ag(s)\] at\[25{}^\circ C,E_{cell}^{o}=0.47V,R=8.314\,J{{K}^{-1}}\] \[F=96500\,C\]:

    A) \[1.8\times {{10}^{15}}\]             

    B)        \[8.5\times {{10}^{15}}\]

    C) \[1.8\times {{10}^{10}}\]             

    D)        \[85\times {{10}^{15}}\]

    Correct Answer: B

    Solution :

    \[E_{cell}^{o}=\frac{0.059}{2}\log {{K}_{c}}\] \[\log {{K}_{c}}=\frac{E_{cell}^{o}\times 2}{0.059}\] \[\log {{K}_{c}}=\frac{0.47\times 2}{0.059}\] \[{{K}_{c}}=8.5\times {{10}^{15}}\]


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