CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2006

  • question_answer
    For which of the following sparingly soluble salt, the solubility (s) and solubility product \[({{K}_{sp}})\]are related  by  the  expression \[s={{({{K}_{sp}}/4)}^{1/3}}\]?

    A) \[BaS{{O}_{4}}\]              

    B)        \[C{{a}_{3}}{{(P{{O}_{4}})}_{2}}\]

    C) \[H{{g}_{2}}C{{l}_{2}}\] 

    D)        \[A{{g}_{3}}P{{O}_{4}}\]

    E) \[CuS\]

    Correct Answer: C

    Solution :

    \[H{{g}_{2}}C{{l}_{2}}\underset{s}{\mathop{Hg_{2}^{2+}}}\,+\underset{2s}{\mathop{2C{{l}^{-}}}}\,\] \[{{K}_{sp}}=[Hg_{2}^{2+}]{{[C{{l}^{-}}]}^{2}}\] \[=(s){{(2s)}^{2}}\] \[{{K}_{sp}}=4{{s}^{3}}\] \[s={{\left( \frac{{{K}_{sp}}}{4} \right)}^{1/3}}\]


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