CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2006

  • question_answer
    One mole of acidified\[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]on reaction with excess KI will liberate ....... mole(s) of \[{{I}_{2}}\]:

    A) 6                                             

    B) 1

    C) 7                             

    D)        2

    E) 3

    Correct Answer: E

    Solution :

    \[C{{r}_{2}}O_{7}^{2-}+14{{H}^{+}}+6{{e}^{-}}\xrightarrow[{}]{{}}2C{{r}^{3+}}+7{{H}_{2}}O\] \[\begin{align}   & \underline{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(2{{I}^{-}}\xrightarrow{{}}{{I}_{2}}+2{{e}^{-}})\times 3} \\  & C{{r}_{2}}O_{7}^{2-}+14{{H}^{+}}+6{{I}^{-}}\xrightarrow{{}} \\ \end{align}\]            \[2C{{r}^{3+}}+7{{H}_{2}}O+3{{I}_{2}}\] Hence, number of moles of\[{{I}_{2}}\]produced = 3


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