CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2007

  • question_answer
    Match List-I with List-II. Choose the correct matching codes from the choices given.
    List - I (Hydride) List - II (Type of hydride)
    A. \[B{{e}_{2}}{{H}_{2}}\] 1. Complex
    B. \[As{{H}_{3}}\] 2. Lewis acid
    C. \[{{B}_{2}}{{H}_{6}}\] 3. Interstitial
    D. \[La{{H}_{3}}\] 4. Covalent
    E. \[LiAl{{H}_{4}}\] 5. Intermediate
    6. Ionic

    A)  A-6, B-2, C-4, D-5, E-1

    B)  A-6, B-2, C-4, D-3, E-1

    C)  A-6, B-4, C-2, D-3, E-5

    D)  A-6, B-4, C-2, D-3, E-1

    E)  A-5, B-4, C-2, D-3, E-1

    Correct Answer: E

    Solution :

    Complex Addition compounds which do not give all their constituent ions when dissolved in water, individual identity of ions are lost, eg, \[-[Cu{{(N{{H}_{3}})}_{4}}]S{{O}_{4}},\,LiAl{{H}_{4}}\]etc. Lewis acid- Electron deficient species which gain electrons while forming a bond with Lewis bases. eg,\[-{{B}_{2}}{{H}_{6}}\]. Interstitial metal hydrides-\[f-\]block hydrides are non-stoichiometric eg,\[La{{H}_{n}}\]etc, where chemical composition is variable\[eg,-\] \[La{{H}_{2.87}},{{X}_{b}}{{H}_{2.5}}\]etc. Intermediate hydride- Polymeric in nature eg, \[Be{{H}_{2}}\] Covalent hydride- Bond forms by sharing of electron, eg,\[As{{H}_{3}}\].


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