CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2008

  • question_answer
    The electronic configuration of the element with maximum electron affinity is

    A) \[1{{s}^{2}},\text{ }2{{s}^{2}},\text{ }2{{p}^{3}}\]

    B) \[1{{s}^{2}},\text{ }2{{s}^{2}},\text{ }2{{p}^{5}}\]

    C) \[1{{s}^{2}},\text{ }2{{s}^{2}},\text{ }2{{p}^{6}},\text{ }3{{s}^{2}},\text{ }3{{p}^{5}}\]

    D) \[1{{s}^{2}},\text{ }2{{s}^{2}},\text{ }2{{p}^{6}},\text{ }3{{s}^{2}},\text{ }3{{p}^{3}}\]

    E)  \[1{{s}^{2}},\text{ }2{{s}^{2}},\text{ }2{{p}^{6}},\text{ }3{{s}^{1}}\]

    Correct Answer: C

    Solution :

    Generally electron affinity increases in a period and decreases in a group but due to smaller size and high electron density on fluorine atom, it experience high intereltronic repulsions. Thus,\[{{F}^{-}}\]ion is less stable in comparison to\[C{{l}^{-}}\]ion. Hence, electron affinity is highest for chlorine. Its electronic configuration is \[_{17}Cl=1{{s}^{2}},2{{s}^{2}},2{{p}^{6}},3{{s}^{2}},3{{p}^{5}}\]


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