CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2011

  • question_answer
    Which one of the following on hydrolysis, gives the corresponding metallic hydroxide, \[{{H}_{2}}{{O}_{2}}\]and\[{{O}_{2}}\]?

    A)  \[L{{i}_{2}}O\]                                 

    B)  \[N{{a}_{2}}{{O}_{2}}\]

    C)  \[Na{{O}_{2}}\]               

    D)         \[N{{a}_{2}}O\]

    E)  \[BeO\]

    Correct Answer: C

    Solution :

    On hydrolysis, alkali metal oxides give the corresponding metallic hydroxides. \[L{{i}_{2}}O+{{H}_{2}}O\xrightarrow{{}}2LiOH\] \[N{{a}_{2}}O+{{H}_{2}}O\xrightarrow{{}}2NaOH\] The peroxides of alkali metals give the corresponding metallic hydroxide and\[{{H}_{2}}{{O}_{2}}\]. \[N{{a}_{2}}{{O}_{2}}+2{{H}_{2}}O\xrightarrow{{}}2NaOH+{{H}_{2}}{{O}_{2}}\] Whereas, the superoxides of alkali metals give the corresponding metallic hydroxide,\[{{H}_{2}}{{O}_{2}}\] and\[{{O}_{2}}\]. \[2Na{{O}_{2}}+2{{H}_{2}}O\xrightarrow{{}}2NaOH+{{H}_{2}}{{O}_{2}}+{{O}_{2}}\] \[Be{{(OH)}_{2}}\]cannot be prepared by hydrolysis of \[BeO,\]as it is insoluble in water.


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