CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2000

  • question_answer
    The fatty acid that shows reducing property is:

    A)  acetic acid         

    B)  ethanoic acid

    C)  oxalic acid          

    D)  formic acid

    Correct Answer: D

    Solution :

    The fatty acid that shows reducing property is formic acid. Formic acid have both groups carboxylic as well as aldehyde \[\underset{\text{Formic}\,\text{acid}}{\mathop{H-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH}}\,\,\underset{\text{Carboxylic}\,\text{group}}{\mathop{H-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH}}\,\,\underset{\text{Aldehyde}}{\mathop{H-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH}}\,\,\] This aldehyde group reduces Tollen's reagent \[\underset{\text{Formic}\,\text{acid}}{\mathop{HCOOH}}\,+A{{g}_{2}}O\xrightarrow{\text{Ammonical}\text{AgN}{{\text{O}}_{\text{3}}}}\]                                 \[{{H}_{2}}O+\underset{\text{Silver}\,\text{mirror}}{\mathop{C{{O}_{2}}+2Ag}}\,\]


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