A) \[{{C}_{2}}{{H}_{5}}Cl+{{C}_{6}}{{H}_{5}}COCl+POC{{l}_{3}}+HCl\]
B) \[{{C}_{2}}{{H}_{5}}Cl+{{C}_{6}}{{H}_{5}}COCl+POC{{l}_{3}}\]
C) \[C{{H}_{3}}COCl+{{C}_{6}}{{H}_{5}}COCl+POC{{l}_{3}}\]
D) \[{{C}_{2}}{{H}_{5}}Cl+{{C}_{6}}{{H}_{5}}COOH+POC{{l}_{3}}\]
Correct Answer: B
Solution :
\[PC{{l}_{5}}\] is a chlorinating agent. It adds to ethyl benzoate to give ethyl chloride and benzoyl chloride. \[{{C}_{6}}{{H}_{5}}COO{{C}_{2}}{{H}_{5}}\xrightarrow{PC{{l}_{5}}}{{C}_{6}}{{H}_{5}}COCl\]\[+\,{{C}_{2}}{{H}_{5}}Cl+POC{{l}_{3}}\]
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