CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2008

  • question_answer
    The angle strain in cyclobutane is

    A)  \[{{24}^{o}}44'\]                             

    B)  \[{{29}^{o}}16'\]

    C)  \[{{19}^{o}}22'\]                             

    D)  \[{{9}^{o}}44'\]

    Correct Answer: D

    Solution :

    When carbon is bonded to four other atoms, the angle between any pair of bonds \[={{109}^{o}},28'\] (tetrahedral angle) but the ring of cyclobutane is square with four angles of \[{{90}^{o}}\]. So, deviation of the bond angle (angle strain) in cyclobutane       \[={{109}^{o}}28'-{{90}^{o}}/2\]                                                 \[={{19}^{o}}28'/2={{9}^{o}}=44'\]


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