CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2011

  • question_answer
    Which one of the following is an intermediate in the reaction of benzene with \[C{{H}_{3}}Cl\] in the presence of anhydrous \[AlC{{l}_{3}}\]?

    A)  \[C{{l}^{-}}\]                                     

    B)  \[CH_{3}^{-}\]

    C)  \[CH_{3}^{+}\]                                

    D)   

    Correct Answer: C

    Solution :

    Mechanism                 \[C{{H}_{3}}Cl+AlC{{l}_{3}}\xrightarrow{{}}CH_{3}^{+}+AlCl_{4}^{-}\]                 \[{{H}^{+}}+AlCl_{4}^{-}\xrightarrow{{}}HCl+AlC{{l}_{3}}\]


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