CET Karnataka Medical CET - Karnataka Medical Solved Paper-2006

  • question_answer
    When a quantity of electricity is passed through \[CuS{{O}_{4}}\]solution, \[0.16g\]of copper gets deposited. If the same quantity of electricity is passed through acidulated water, then the volume of \[{{H}_{2}}\] liberated at STP will be: [given: atomic weight of \[Cu=64\]]

    A)  \[4.0c{{m}^{3}}\]       

    B)  \[56c{{m}^{3}}\]

    C)  \[604c{{m}^{3}}\]     

    D)  \[8.0c{{m}^{3}}\]

    Correct Answer: B

    Solution :

    \[\frac{Wt.\,\,of\,\,Cu\,deposited}{Wt.\,\,of\,{{H}_{2}}\,produced}=\frac{Eq.\,wt.\,of\,Cu}{Eq.\,wt.\,\,of\,H}\] \[\frac{0.16}{wt.\,of\,{{H}_{2}}}=\frac{64/2}{1}=\frac{32}{1}\] wt. of \[{{H}_{2}}=\frac{0.16}{32}=5\times {{10}^{-3}}g\] Volume of \[{{H}_{2}}\] liberated at STP \[=\frac{22400}{2}\times 5\times {{10}^{-3}}cc\] \[=56cc\]


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