CET Karnataka Medical CET - Karnataka Medical Solved Paper-2007

  • question_answer
    Which complex cannot ionise in solution?

    A)  \[[CoC{{l}_{3}}{{(N{{H}_{3}})}_{3}}]\]

    B)  \[{{K}_{4}}[Fe{{(CN)}_{6}}]\]

    C)  \[{{K}_{2}}[Pt({{F}_{6}})]\]    

    D)  \[[Pt{{(N{{H}_{3}})}_{6}}]C{{l}_{4}}\]

    Correct Answer: A

    Solution :

    \[[CoC{{l}_{3}}{{(N{{H}_{3}})}_{3}}]\] cannot ionise in solution because three chloride ions satisfy primary and secondary valencies. It will not be precipitated by the addition of  \[AgN{{O}_{3}}\].


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