CET Karnataka Medical CET - Karnataka Medical Solved Paper-2008

  • question_answer
    The overlapping of orbitals in benzene is of the type

    A)  \[sp-sp\]          

    B)  \[p-p\]

    C)  \[s{{p}^{2}}-s{{p}^{2}}\]        

    D)  \[s{{p}^{3}}-s{{p}^{3}}\]

    Correct Answer: C

    Solution :

    The molecular orbital picture of benzene shows that in it all the six carbon atoms are \[s{{p}^{2}}\]hybridised. Out of these three sp2 hybrid orbitals of each C atom, two orbitals overlap with \[s{{p}^{2}}\] hybrid orbitals of adjacent C atoms to form six \[C-C\] single bonds. The remaining \[s{{p}^{2}}\] orbital of each C atom overlaps with s-orbital of each hydrogen atom to form six \[C-H\] single sigma bonds. Each C atom is now left with one unhybridisedp-orbital perpendicular to the plane of the ring.


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