Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2007

  • question_answer
    The rate of reaction between two reactants A and B decreases by a factor of 4 if the concentration of reactant B is doubled. The order of this reaction with respect to reactant B is

    A)  \[2\]                                    

    B)  \[-1\]

    C)  \[1\]                                    

    D)  \[-2\]

    Correct Answer: D

    Solution :

    Rate of reaction  \[=k{{[concentration\text{ }of\text{ }reactant]}^{n}}\] Rate of reaction \[=k{{[B]}^{n}}\]        .....(i) where, n = order of reaction. If concentration of B is doubled the rate of reaction decreases by a factor of 4                 \[\frac{rate\,\,of\,\,rection}{4}=k{{[2B]}^{n}}\] ?.(ii) Dividing Eqs. (i) by (ii) \[\Rightarrow \]               \[\frac{rate\,of\,reaction}{rate\,of\,reaction}\times 4=\frac{k{{[B]}^{n}}}{k{{[2B]}^{n}}}\] \[\Rightarrow \]               \[\frac{4}{1}={{\left( \frac{1}{2} \right)}^{n}}\] \[\therefore \]  \[n=-2\]


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