Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2007

  • question_answer
    Most stable ion is

    A)  \[{{C}_{6}}{{H}_{5}}CH_{2}^{+}\]       

    B)  \[{{(C{{H}_{3}})}_{3}}-{{C}^{+}}\]

    C)  \[{{(C{{H}_{3}})}_{2}}C{{H}^{+}}\]

    D)  \[C{{H}_{3}}CH_{2}^{+}\]

    Correct Answer: A

    Solution :

    Order of stability of carbocation. \[{{({{C}_{6}}{{H}_{5}})}_{3}}{{C}^{+}}>{{({{C}_{6}}{{H}_{5}})}_{2}}C{{H}^{\oplus }}>{{C}_{6}}{{H}_{5}}\overset{\oplus }{\mathop{C}}\,{{H}_{2}}\] \[>\overset{+}{\mathop{C}}\,{{H}_{2}}-CH=C{{H}_{2}}>{{(C{{H}_{3}})}_{3}}\overset{+}{\mathop{C}}\,>{{(C{{H}_{3}})}_{2}}\overset{+}{\mathop{C}}\,H\] \[>C{{H}_{3}}\overset{+}{\mathop{C}}\,{{H}_{2}}>\overset{+}{\mathop{C}}\,{{H}_{3}}\]


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