Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2010

  • question_answer
    In the lead-acid battery during charging, the cathode reaction is

    A)  reduction of \[P{{b}^{2+}}\] to \[Pb\]

    B)  formation of \[PbS{{O}_{4}}\]

    C)  deposition of \[Pb\] at the anode

    D)  formation of \[Pb{{O}_{2}}\]

    Correct Answer: A

    Solution :

    When a lead acid battery is charged, following reactions occur at anode and cathode. At anode: \[PbS{{O}_{4}}+2{{H}_{2}}O\xrightarrow{{}}Pb{{O}_{2}}+3{{H}^{+}}+HSO_{4}^{-}+2{{e}^{-}}\]At cathode: \[P{{b}^{2+}}+{{H}^{+}}+2{{e}^{-}}\xrightarrow{{}}Pb+HSO_{4}^{-}\] Thus, at cathode reduction of \[P{{b}^{2+}}\] to \[Pb\]occurs.


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