Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2011

  • question_answer
    When chlorine reacts with dil. \[NaOH\]under cold conditions, the oxidation state of chlorine changes from zero to

    A)  \[-1\] and \[+5\]    

    B)  \[+1\] and \[+4\]

    C)  \[+5\] and \[+3\]   

    D)  \[-1\] and \[+1\]

    Correct Answer: D

    Solution :

    When chlorine reacts with dilute and cold \[NaOH,\]sodium chloride and sodium hypochloride are formed. \[2NaOH\,(cold)+C{{l}_{2}}\]\[\xrightarrow{{}}NaCl+\underset{hypochloride}{\mathop{\underset{sodium}{\mathop{NaClO}}\,}}\,+{{H}_{2}}O\] Let oxidation state of \[Cl\]in \[NaCl\]is x.                                 \[NaCl\]                                 \[+1+x=0\]                                                 \[x=-1\] Let oxidation state of \[Cl\] in \[NaClO\]is x.                                 \[NaClO\]                                 \[1+x-2=0\]                                 \[x-1=0\]                                                 \[x=+1\] \[\therefore \]Oxidation states of chlorine changes from 0 to  \[-1\] and \[+1\].


You need to login to perform this action.
You will be redirected in 3 sec spinner