Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2011

  • question_answer
    1-butyne on hydration gives

    A)  butan-1, 2-diol  

    B)  butan-1-ol

    C)  butan-2-ol       

    D)  butan-2-one

    Correct Answer: D

    Solution :

    \[\underset{1-butyne}{\mathop{C{{H}_{3}}C{{H}_{2}}C\equiv CH}}\,+{{H}_{2}}O\xrightarrow{HgS{{O}_{4}}/{{H}_{2}}S{{O}_{4}}}\] \[C{{H}_{3}}C{{H}_{2}}\overset{OH}{\mathop{\overset{|}{\mathop{C}}\,}}\,=C{{H}_{2}}\xrightarrow{+{{H}_{2}}O}\underset{(unstable)}{\mathop{C{{H}_{3}}C{{H}_{2}}-\underset{OH}{\mathop{\underset{|}{\mathop{\overset{OH}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\] \[\xrightarrow[-{{H}_{2}}O]{}\underset{\text{butan}\,\text{-2-one}}{\mathop{C{{H}_{3}}C{{H}_{2}}-\underset{O}{\mathop{\underset{||}{\mathop{C}}\,}}\,-C{{H}_{3}}}}\,\]


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