CMC Medical CMC-Medical Ludhiana Solved Paper-2008

  • question_answer
    The oxidation state of S in\[{{H}_{2}}{{S}_{2}}{{O}_{8}}\] is

    A)  + 2                                        

    B)  + 4

    C)  + 6                                        

    D)  + 7

    Correct Answer: C

    Solution :

                    The chemical structure of \[{{H}_{2}}{{S}_{2}}{{O}_{8}}\] is as follows : \[H-O-\underset{O}{\overset{O}{\mathop{\underset{\mathbf{||}}{\overset{\mathbf{||}}{\mathop{S}}}\,}}}\,-O-O-\underset{O}{\overset{O}{\mathop{\underset{\mathbf{||}}{\overset{\mathbf{||}}{\mathop{S}}}\,}}}\,-O-H\] Let the oxidation number of S is x. \[\begin{matrix}    \,\,\,\,2\times (+1) & +2\times x & +6\times (-2) & +2\times (-1)  \\    \text{For}\,\text{H} & \text{for}\,\,\text{S} & \text{for}\,\,\text{O} & \text{for}\,\text{(O}-\text{O)}  \\ \end{matrix}\] \[2+2x-12-2=0\] \[2x=12\] \[x=+6\]


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