CMC Medical CMC-Medical VELLORE Solved Paper-2008

  • question_answer
    Which one of the following electrolytes would dissolve in water to give an alkaline solution?

    A)  \[C{{H}_{3}}COOH\]     

    B)  \[C{{H}_{3}}COONa\]

    C)  \[N{{H}_{4}}Cl\]                              

    D)  \[HCN\]

    E)  \[NaCl\]            

    Correct Answer: B

    Solution :

                    \[C{{H}_{3}}COONa\]will give an alkaline solution on dissolving in water because it is a salt of strong base and weak acid. \[C{{H}_{3}}COONa+{{H}_{2}}O\rightleftharpoons \underset{\begin{smallmatrix}  highly \\  ionised \end{smallmatrix}}{\mathop{NaOH}}\,+\underset{\begin{smallmatrix}  feebly \\  ionised \end{smallmatrix}}{\mathop{C{{H}_{3}}COOH}}\,\] So, in solution the concentration of \[O{{H}^{-}}\] ion is higher than\[{{H}^{+}}\]concentration. Hence, aqueous solution of \[C{{H}_{3}}COONa\] is alkaline.


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