CMC Medical CMC-Medical VELLORE Solved Paper-2010

  • question_answer
    The most suitable reagent for the conversion of \[RC{{H}_{2}}OH\xrightarrow{{}}RCHO\]is

    A)  \[KMn{{O}_{4}}\]

    B)  \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]

    C)  \[Cr{{O}_{3}}\]

    D)  PCC (pyridine chloro chromate)

    E)  None of the above

    Correct Answer: D

    Solution :

                    Strong oxidising agents such as\[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]convert alcohol directly to carboxylic acid. However oxidation can be stopped at aldehyde stage by using \[Cr{{O}_{3}}\]in anhydrous medium. PCC (pyridinium chloro chromate) is a better oxidising agent because it stopped the oxidation of primary alcohol at aldehydic stage. \[RC{{H}_{2}}OH\xrightarrow{PCC}RCHO\]


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