A) \[{{(C{{H}_{3}})}_{3}}C\cdot Cl\]
B) \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}Cl\]
C) \[C{{H}_{3}}C{{H}_{2}}Cl\]
D) \[C{{H}_{3}}Cl\]
E) None of these
Correct Answer: A
Solution :
The order of reactivity of\[{{S}_{N}}1\]reaction depends upon the stability of carbocation in the first step. Greater the stability of the carbocation, greater will be the ease of formation and hence faster will be the rate of reaction. The order of reactivity will be \[3{}^\circ \]alkyl halide > \[2{}^\circ \]alkyl halide > \[1{}^\circ \]alkyl halide > methyl halide Hence,\[{{(C{{H}_{3}})}_{3}}Cl\cdot Cl\]is most reactive towards\[{{S}_{N}}1\]mechanism.
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