CMC Medical CMC-Medical VELLORE Solved Paper-2011

  • question_answer
    Phenol can be distinguished from ethanol by the following reagents except

    A)  sodium

    B)  \[NaOH\text{/}{{I}_{2}}\]

    C)  neutral \[FeC{{l}_{3}}\]

    D)  \[B{{r}_{2}}\text{/}{{H}_{2}}O\]

    E)  phthalic anhydride/cone. \[{{H}_{2}}S{{O}_{4}}\] and \[NaOH\]

    Correct Answer: A

    Solution :

                    Phenol cannot be distinguished from ethanol by sodium because both evolve hydrogen with sodium. \[2{{C}_{6}}{{H}_{5}}OH+2Na\xrightarrow{{}}2{{C}_{6}}{{H}_{5}}ONa+{{H}_{2}}\uparrow \] \[2{{C}_{2}}{{H}_{5}}OH+2Na\xrightarrow{{}}2{{C}_{2}}{{H}_{5}}ONa+{{H}_{2}}\uparrow \]


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