CMC Medical CMC-Medical VELLORE Solved Paper-2011

  • question_answer
    One mole of acidified \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]on reaction with excess KI will liberate ?... mole(s) of \[{{I}_{2}}\].

    A)  6                                            

    B)  1

    C)  7                                            

    D)  2

    E)  3

    Correct Answer: E

    Solution :

                    \[\begin{align}   & \underline{\begin{align}   & C{{r}_{2}}O_{7}^{2-}+14{{H}^{+}}+6{{e}^{-}}\xrightarrow{{}}2C{{r}^{3+}}+7\,{{H}_{2}}O \\  & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(2{{I}^{-}}\xrightarrow{{}}{{I}_{2}}+2{{e}^{-}})\times 3 \\ \end{align}} \\  & C{{r}_{2}}O_{7}^{2-}+14\,{{H}^{+}}+6{{I}^{-}}\xrightarrow{{}} \\  & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,2C{{r}^{3+}}+7{{H}_{2}}O+3{{I}_{2}} \\ \end{align}\] Hence, number of moles of \[{{I}_{2}}\]produced = 3


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