CMC Medical CMC-Medical VELLORE Solved Paper-2014

  • question_answer
    The addition of HBr to an alkene in the presence of peroxide is the example of

    A)  electrophilic addition reaction

    B)  nucleophilic addition reaction

    C)  free radical addition reaction

    D)  the formation of carbocation as an intermediate

    Correct Answer: C

    Solution :

              Addition of HBr to an alkene in the presence of peroxide is the example of free radical addition reaction. \[R-O-O-R\xrightarrow{{}}2R-{{O}^{\bullet }}\] \[R-{{O}^{\bullet }}+HBr\xrightarrow{{}}R-OH+B{{r}^{\bullet }}\] \[R-CH=C{{H}_{2}}+B{{r}^{\bullet }}\xrightarrow{{}}R-\overset{\bullet }{\mathop{CH}}\,-C{{H}_{2}}Br\] \[R-\overset{\bullet }{\mathop{CH}}\,-C{{H}_{2}}Br\xrightarrow{HBr}RC{{H}_{2}}C{{H}_{2}}Br+B{{r}^{\bullet }}\] \[B{{r}^{\bullet }}+B{{r}^{\bullet }}\xrightarrow{{}}B{{r}_{2}}\]


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