Haryana PMT Haryana PMT Solved Paper-2005

  • question_answer
    In nitration of benzene, cone. \[HN{{O}_{3}}\] acts  as:

    A)  base          

    B)  acid                     

    C)  reducing agent

    D)  catalyst       

    Correct Answer: D

    Solution :

                    In     nitrating     mixture  \[(conc.\,HN{{O}_{3}}+conc.\,{{H}_{2}}S{{O}_{4}})\]. ) cone. \[HN{{O}_{3}}\] acts as base i.e., it accepts proton and give nitronium ion (the electrophile). \[HN{{O}_{3}}+{{H}_{2}}S{{O}_{4}}\xrightarrow{{}}\underset{nitronium\,ion}{\mathop{\underset{NO_{2}^{+}}{\mathop{\underset{\downarrow {{H}_{2}}O}{\mathop{{{H}_{2}}NO_{3}^{+}}}\,}}\,}}\,+HSO_{4}^{-}\]


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