J & K CET Engineering J and K - CET Engineering Solved Paper-2003

  • question_answer
    Correct order of first ionization potential among the following elements Be, B, C, N, O is

    A)  \[B<Be<C<O<N\]

    B)  \[B<Be<C<N<O\]

    C) \[~Be<B<C<N<\text{O}\]

    D) \[~Be<B<C<O<N\]

    Correct Answer: A

    Solution :

     The ionisation potential increases from left to right in a period but -the first ionisation potential of nitrogen is greater than oxygen due to half-filled stable configuration and ionisation potential of Be is greater than B due to completely filled s-orbital. Hence, the order of ionisation potential is as: \[\begin{align}   & \text{Element:}\,\,\,B\,\,\,<\,\,\,Be\,\,\,\,\,<\,\,\,\,C\,\,\,\,<\,\,\,\,O\,\,\,\,\,\,\,\,<\,\,\,\,N\, \\  & \text{IP(eV)}\,\,\,\,\,\,8.3\,\,\,\,\,\,\,\,\,9.3\,\,\,\,\,\,\,\,\,11.2\,\,\,\,\,\,\,13.6\,\,\,\,\,\,14.5\, \\ \end{align}\]


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