J & K CET Engineering J and K - CET Engineering Solved Paper-2003

  • question_answer
    The compound obtained by heating a mixture of\[{{\text{1}}^{\text{o}}}\]amine and chloroform with ethanolic potassium hydroxide is

    A)  an alkyl isocyanide             

    B)  an alkyl isothiocyanate

    C)  an amide                    

    D)  an amide and nitro compound

    Correct Answer: A

    Solution :

     Primary amines on heating with chloroform and ethanolic KOH, give alkyl isocyanide. This reaction is called carbylamine reaction. \[\underset{{{1}^{o}}\text{amine}}{\mathop{R-N{{H}_{2}}}}\,+CHC{{l}_{3}}+\underset{(alcohol)}{\mathop{3KOH}}\,\xrightarrow{\Delta }\underset{\text{alkyl}\,\text{isocyanide}}{\mathop{R-NC}}\,\]


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