J & K CET Engineering J and K - CET Engineering Solved Paper-2006

  • question_answer
    The bond dissociation energy of \[\text{C}{{\text{l}}_{\text{2}}}\text{, B}{{\text{r}}_{\text{2}}}\]and \[{{\text{I}}_{\text{2}}}\]follow the order

    A) \[~C{{l}_{2}}>{{I}_{2}}>B{{r}_{2}}\] 

    B)  \[{{I}_{2}}>B{{r}_{2}}>C{{l}_{2}}\]

    C) \[{{I}_{2}}=C{{l}_{2}}=B{{r}_{2}}\]

    D) \[C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}\]

    Correct Answer: D

    Solution :

     The bond dissociation energy of \[C{{l}_{2}},B{{r}_{2}}\]and \[{{I}_{2}}\]is as: \[\begin{align}   & \text{Molecule:}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{l}_{2}}\,\,\,\,\,>\,\,\,\,B{{r}_{2}}\,\,\,\,\,\,>\,\,{{I}_{2}} \\  & \text{Disscociation:}\,\,\,\,\,242.6\,\,\,\,\,\,\,192.8\,\,\,\,\,\,\,151.1 \\  & \text{enthalpy}\,(kJ\,mo{{l}^{-1}}) \\ \end{align}\]


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