J & K CET Engineering J and K - CET Engineering Solved Paper-2006

  • question_answer
    The product formed in the reaction of glycine with benzoyl chloride \[\text{+ aq NaOH}\]is

    A) \[~PhCOC{{H}_{2}}N{{H}_{2}}\]

    B) \[~PhC{{H}_{2}}N{{H}_{2}}\]

    C) \[~PhCONHC{{H}_{3}}\]

    D) \[~PhCONHC{{H}_{2}}C{{O}_{2}}H\]

    Correct Answer: D

    Solution :

     Glycine reacts with benzoyl chloride in the presence of aq. NaOH to give benzoylglycine (Hippuricacid). \[\underset{\text{glycine}}{\mathop{HOOC.C{{H}_{2}}N{{H}_{2}}}}\,+\underset{\text{benzoyl}\,\text{chloride}}{\mathop{PhCOCl}}\,\xrightarrow[\Delta ]{aq.NaOH}\] \[\underset{\begin{smallmatrix}  \text{benzoyl}\,\text{glycine} \\  (Hippuric\,acid) \end{smallmatrix}}{\mathop{PhCONHC{{H}_{2}}COOH}}\,+HCl\]


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