J & K CET Engineering J and K - CET Engineering Solved Paper-2009

  • question_answer
    The IUPAC name of the molecule \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{C}}\,}}\,=\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{C}}\,}}\,-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH\]

    A)  4-oxo-2, 3-dimethyl pent-2-en-l-oic acid

    B)  2-carboxy-3 methyl pent-2-en-3-one

    C)  4-carboxy-3 methyl pent-3-en-2-one

    D)  2, 3-dimethyl-4-oxo pent-2-en-l-oic acid

    Correct Answer: D

    Solution :

     The order of preference is \[-COOH>>C=O\] Thus, \[\overset{5}{\mathop{C}}\,{{H}_{3}}-\overset{O}{\mathop{\overset{4||}{\mathop{C}}\,}}\,-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{3}{\mathop{C}}}\,}}\,=\underset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{2}{\mathop{C}}}\,}}\,-\overset{O}{\mathop{\overset{||1}{\mathop{C}}\,}}\,-OH\] 2, 3-dimethyl-4-oxopent-2-en-1-oic acid


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