J & K CET Engineering J and K - CET Engineering Solved Paper-2010

  • question_answer
    The correct order of decreasing acidic nature of \[Hp,\text{ }ROH,CH\equiv CH\]and\[N{{H}_{3}}\] is

    A)  \[CH\equiv CH>{{H}_{2}}O>ROH>N{{H}_{3}}\]

    B)  \[{{H}_{2}}O\,>ROH>CH\equiv CH>N{{H}_{3}}\]

    C)  \[ROH>N{{H}_{3}}>CH\equiv CH>{{H}_{2}}O\]

    D)  \[{{H}_{2}}O>ROH>N{{H}_{3}}>CH\equiv CH\]

    Correct Answer: B

    Solution :

     The conjugated bases of the given compounds are as \[O{{H}^{-}},R{{O}^{-}},CH\equiv {{C}^{-}},NH_{2}^{-}\] Higher the stability of conjugate base, higher is the ease to donate a proton and thus, higher is the acidity. Thus, the order of acidic nature is \[{{H}_{2}}O>ROH>CH\equiv CH>N{{H}_{3}}\]


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