J & K CET Engineering J and K - CET Engineering Solved Paper-2012

  • question_answer
    The correct order of electron gain enthalpy \[({{\Delta }_{eg}}H)\] of the halogen atoms is

    A) \[F<Cl<Br<I\]   

    B) \[~Cl<F<Br<~I\]

    C) \[~I<Br<Cl<F\]   

    D) \[~Cl<Br<I<F\text{ }\]

    Correct Answer: B

    Solution :

     The correct order of electron gain enthalpy\[\Delta H\] (with + sign) of the halogen atom is \[Cl<F<Br<I\] The reason that fluorine has a less negative electron affinity than chlorine is relatively   small size of F atom resulting in the repulsions   (electron-electron)   to   the entering electron.


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