J & K CET Medical J & K - CET Medical Solved Paper-2015

  • question_answer
    For the reaction \[A(s)+2{{B}^{+}}(aq)\to {{A}^{2+}}(aq)+2B(s);\] the\[E{}^\circ \]is 1.18 V. Then the equilibrium constant for the reaction is

    A)  1010

    B)  1020

    C)  1040

    D)  1060

    Correct Answer: C

    Solution :

     \[A(s)+2{{B}^{+}}(aq)\xrightarrow{{}}{{A}^{2+}}(aq)+2B(s)\] Oxidation \[A(s)\xrightarrow{{}}{{A}^{2+}}(aq)+2{{e}^{-}}\] Reduction \[2{{B}^{+}}(aq)+2{{e}^{-}}\xrightarrow{{}}2B(s)\] Here,           \[n=2\] \[E{}^\circ =1.18V\] \[{{E}_{eq}}=?\] \[\because \] \[\log {{K}_{eq}}=\frac{nE{}^\circ F}{RT}\]           \[\left[ \frac{F}{RT}=\frac{1}{0.059} \right]\] \[\therefore \] \[\log {{K}_{eq}}=\frac{2\times 1.18\times 1}{0.059}\] \[\therefore \] \[\log {{K}_{eq}}=40\]or \[{{K}_{eq}}={{10}^{40}}\]


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