JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2004

  • question_answer
        \[O{{H}^{-}}\], product X is :

    A)  ethylene bromide

    B)  vinyl bromide

    C)  bromo ethane

    D)  ethyledine bromide

    Correct Answer: B

    Solution :

                    Glycerol is dehydrated on heating with\[\text{KHS}{{\text{O}}_{\text{4}}}\]. \[\underset{\begin{smallmatrix}  | \\  C{{H}_{2}}OH  \\  glu\operatorname{c}erol \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{2}}OH \\  | \end{smallmatrix}}{\mathop{CHOH}}}\,\xrightarrow[\Delta ]{KHS{{O}_{4}}}\underset{\begin{smallmatrix}  | \\  \underset{Acraldehyde\,or\,acrolein}{\mathop{CHO}}\, \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{2}} \\  |\,\,\,\,\,| \end{smallmatrix}}{\mathop{CH}}}\,+2{{H}_{2}}O\]


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