JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2006

  • question_answer
        Which of the following is correct for the reaction? \[{{N}_{2}}(g)+3{{H}_{2}}(g)2N{{H}_{3}}(g)\]

    A)  \[{{K}_{p}}={{K}_{c}}\]

    B)  \[{{K}_{p}}<{{K}_{c}}\]

    C)  \[{{K}_{p}}>{{K}_{c}}\]

    D)  Pressure is required to predict the correlation

    Correct Answer: B

    Solution :

                    Key Idea: \[{{K}_{p}}={{K}_{c}}{{(RT)}^{\Delta n}}\] Find the value of\[\Delta n\]from the given equation to find relation between\[{{K}_{p}}\]and\[{{K}_{c}}\]                 \[{{N}_{2}}(g)+3{{H}_{2}}(g)2N{{H}_{3}}(g)\]                 \[\Delta n={{n}_{p}}-{{n}_{r}}\]                 \[=2-4\]                 \[=-2\] \[\therefore \]  \[{{K}_{p}}={{K}_{c}}{{(RT)}^{-2}}\] Or           \[{{K}_{p}}=\frac{{{K}_{c}}}{{{(RT)}^{2}}}\]                 \[{{K}_{p}}<{{K}_{c}}\]


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